Structural-Stability Relationship in a Series of [ZnX]\(^-\) Inorganic Organic Hybrid Materials

Authors

  • Bikram Singh GGM Science College, Cluster University of Jammu, Jammu 180016,GDC, Billawar, GDC, Akhnoor
  • Sanjay K. Verma GGM Science College, Cluster University of Jammu, Jammu 180016,GDC, Billawar, GDC, Akhnoor
  • Mukesh Kumar GGM Science College, Cluster University of Jammu, Jammu 180016,GDC, Billawar, GDC, Akhnoor
  • Dinesh Jasrotia GGM Science College, Cluster University of Jammu, Jammu 180016,GDC, Billawar, GDC, Akhnoor

DOI:

https://doi.org/10.26713/jamcnp.v5i1.768

Keywords:

Non-covalent interactions, Structure stability, Hg motifs, Mercurophilic interactions and 1D-2D structural parameters

Abstract

To scrutinize the role the weak interactions in structure-stability of [ZnX]- (X = Cl, Br, I) based derivatives, three series of inorganic-organic hybrid materials were studied through single crystal X-ray crystallographic data obtained from IUCr in CIF format. The organic constituent of the hybrid compounds is holding the inorganic moiety through D-H...X interactions, where D is N, C or O of organic moiety acts as H-donor atom and X of inorganic component is Cl, Br I or F behaves as H-acceptor atom.  The structural parameters such as the Zn-X bond distance lies in the range of 2.019(5) í…  [ZnF-3] to 2.730(4) í… [ZnCl-1] and X-Zn-X bond angle has minimum value of 82.35o and maximum value of 180o for [ZnF-3], were calculated. The maximum twist of X-Zn...Zn-X = 179.8(3)o at symmetry position of 0.5+x, 0.5-y, 0.5+z is observed in [ZnBr-7] derivative.

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Published

2018-03-24
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How to Cite

Singh, B., Verma, S. K., Kumar, M., & Jasrotia, D. (2018). Structural-Stability Relationship in a Series of [ZnX]\(^-\) Inorganic Organic Hybrid Materials. Journal of Atomic, Molecular, Condensed Matter and Nano Physics, 5(1), 1–17. https://doi.org/10.26713/jamcnp.v5i1.768

Issue

Vol. 5 No. 1 (2018)

Section

Research Article

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