Effect of Nuclear Radiation Generated Thermal Spike on Degradation Reaction Kinetics of a Polymer SSNTD and Its Impact on Track Diameter
DOI:
https://doi.org/10.26713/jamcnp.v9i1.1953Keywords:
SSNTD, Thermal Spike model, Polymers, Solid State reaction kineticsAbstract
It has been extensively studied that high polymer form an important group of materials used for solid state nuclear track detectors (SSNTD). The radiation induced damage not only leave tracks for microscopic examination but also change other physical properties of the material. One of them being the average molecular mass of the polymer. The change in this parameter which is induced by the radiation exposure can be studied and can give an estimate of the number of polymer chain scission, which has a direct influence on the track diameter and can give an estimate of the energy of radiation deposited inside the sample. From this the energy of the incoming particle flux can be calculated. In this paper a relationship between polymer degradation as given by the extent of the depolymerization reaction, the track diameter and energy of the incoming particle is sought.
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References
G. Bonfiglioli, A. Ferro and A. Mojoni, Electron microscope investigation on the nature of tracks of fission products in mica, Journal of Applied Physics 32 (1961), 2499 – 2503, DOI: 10.1063/1.1728339.
L.T. Chadderton and H.M. Montagu-Pollock, Fission fragment damage to crystal lattices: heat-sensitive crystals, Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences 274(1357) (1963), 239 – 252, DOI: 10.1098/rspa.1963.0127.
L.T. Chadderton and I.McC. Torrens, Fission Damage in Crystals, Methuen, London (1969), DOI: 10.1063/1.3022524.
L.T. Chadderton, D.V. Morgan, I.McC. Torrens and D. Van Vliet, On the electron microscopy of fission fragment damage, The Philosophical Magazine: A Journal of Theoretical Experimental and Applied Physics (Series 8) 13(121) (1966), 185-195, DOI: 10.1080/14786436608211995.
S.J. Charde, S.S. Sonawane, S.H. Sonawane and N.G. Shimpic, Degradation kinetics of polycarbonate composites: kinetic parameters and artificial neural network, Chemical and Biochemical Engineering Quarterly 32(2) (2018), 151 – 165, DOI: 10.15255/CABEQ.2017.1173.
S.A. Durrani and R.K. Bull, Solid State Nuclear Track Detection: Principles, Methods and Applications, Pergamon Press (1987), DOI: 10.1016/C2013-0-02771-5.
J.H. Flynn, Temperature dependence of the rate of reaction in thermal analysis, Journal of Thermal Analysis 36 (1990), 1579 – 1593, DOI: 10.1007/bf01914077.
F. Seitz and J.S. Koehler, Displacement of atoms during irradiation, in: E. Seitz and D. Turnbull (Eds.), Solid State Physics, Vol. 2, Academic Press, London/New York, 305 – 448 (1956).
G. Szenes, Thermal spike analysis of ion-induced tracks in semiconductors, Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms 269(19) (2011), 2075 – 2079, DOI: 10.1016/j.nimb.2011.06.014.
G. Szenes, Thermal spike model of amorphous track formation in insulators irradiated by swift heavy ions, Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms 116(1-4) (1996), 141 – 144, DOI: 10.1016/0168-583X(96)00025-0.
G. Szenes, K. Havancsák, V. Skuratov, P. Hanák, L. Zsoldos and T. Ungár, Application of the thermal spike model to latent tracks induced in polymers, Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms 166-167(2) (2000), 933 – 937, DOI: 10.1016/S0168-583X(99)00733-8.
S. Vyazovkin and C.A. Wight, Model-free and model-fitting approaches to kinetic analysis of isothermal and nonisothermal data, Thermochimica Acta 340 (1999), 53 – 68, DOI: 10.1016/S0040-6031(99)00253-1.
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